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🪨 Geology

Malachite

Malachite is a green copper carbonate hydroxide, Cu₂CO₃(OH)₂, a hardness 3.5 to 4 mineral that forms in the weathered zones of copper deposits.

Malachite is a green copper carbonate hydroxide, Cu₂CO₃(OH)₂, a hardness 3.5 to 4 mineral that forms in the weathered zones of copper deposits. It often grows in grape-like masses with concentric bands, and it has been used as an ore, a pigment and an ornamental stone.

Photograph of Malachite (Cu₂CO₃(OH)₂ • Monoclinic Copper Carbonate)
📷 Photo: TheFurther21 via Wikimedia Commons • CC BY-SA 4.0
🪨 Geology Guide Specimen: Open Malachite in the CRV Science Rock & Mineral ID Guide to log the specimen, compare it with the other 8 mineral classes of Dana / Strunz Classes, and test your eye in LithoClade.

Oxidized Copper: How Does Malachite Form?

When copper sulfides near the surface are weathered by oxygenated, carbonate-bearing water, the copper dissolves and reprecipitates as green carbonates. Malachite forms in this oxidized zone of copper deposits, often with azurite, and it is a useful surface sign of copper below.

Banding: Why Does It Look Like Bullseyes?

Malachite typically forms botryoidal (grape-like) and stalactitic masses with concentric light and dark green bands, produced as layers precipitate one after another. Polished slices give the swirling patterns used in jewelry, boxes and carved columns, as in the famous malachite rooms of Russian palaces.

Ore and Pigment: What Is It Used For?

Malachite is about 57 percent copper and was among the earliest copper ores smelted. Ground malachite was a green pigment in ancient Egypt and in European painting. It fizzes in acid and leaves a pale green streak.

Malachite at a Glance

PropertyValue
Type / varietyCu₂CO₃(OH)₂ • Monoclinic Copper Carbonate
CompositionCu₂CO₃(OH)₂ (57.4 wt% Copper)
Geology Guide groupMinerals (8 Major Chemical Groups)
Mineral GroupCarbonates
Mohs hardnessMohs 3.5–4
Texture / habitBotryoidal (grape-like) masses with concentric light- and dark-green eye banding
Density3.90–4.05 g/cm³
Lustre and cleavageSilky-to-velvety banded emerald and forest green; pale green streak; fizzes in HCl
Geological settingWeathered oxidized upper zones of copper ore deposits worldwide
Diagnostic feature (Geology Guide)Botryoidal (grape-cluster) masses and stalactites sliced to reveal swirling bullseye bands of vivid emerald and forest green (Mohs 3.5–4) that leave a pale green streak and fizz in hydrochloric acid.
FormulaCu₂CO₃(OH)₂
StreakPale green

See Also

  • Azurite — the blue copper carbonate it often forms with
  • Copper — the metal it is mined for
  • Calcite — another carbonate that fizzes in acid
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